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This Is Why The YouTube Kids App Is Being Removed On September 30

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EDITORS NOTE: On September 30, 2018, YouTube Kids will become a separate standalone app and all children’s videos on YouTube will be removed and replaced with a kids-focused

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We report an extensive study of the pH of the Hunter-Meinert triad reaction (HMT) in aqueous solution, using density functional theory (DFT) and ab initio molecular dynamics (AIMD) simulations. Our calculations show that, apart from the homogeneous nucleophilic substitution reaction, the heterogeneous HMT proceeds in several different types of associative and dissociative pathways, in which the neutral species cannot be found. We conclude that a simple proton transfer reaction is preferred and a second-order rate law can be used to predict the pH of the HMT from first-principles. This is in agreement with previous experimental results obtained for the HMT at alkaline conditions. Our findings show that the pH of the HMT can vary by approximately one unit, whereas experimental measurements may deviate by more than one unit. Our results are also discussed with respect to the effect of substituents on the pH of HMT.The objective of this proposal is to investigate the mechanisms which underlie the pathogenesis of systemic lupus erythematosus (SLE). Research proposed for this year will concentrate on two major areas of the research program: 1) characterizing immune complex interactions with cells of the monocyte-macrophage lineage and 2) investigating the role of macrophage function in the pathogenesis of SLE. The proposed research will be performed in close collaboration with several other NIH projects. The importance of this research stems from the fact that the immune complex interactions with cells of the monocyte-macrophage lineage have not been studied extensively and the proposed research on this topic will lead to a greater understanding of monocyte and macrophage function and their role in immune complex disease, especially lupus. This understanding could lead to the development of new strategies for treatment of this disease.

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